Not the prettiest demo, but you'll get the picture

Fill the form and then press Download your document to get a sample Word document

Download your document
Notes:
  1. If you get a .xml file, it means that your browser's UA string doesn't contain the word 'Windows'. It should still open with OpenOffice.org and MS Office.
  2. If you get a .doc file and you use OpenOffice.org, you must change the extension of the downloaded file from .doc to .xml.
  3. Drag the resulting document into a simple text editor window (e.g. Notepad) to see the XML.

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PHP to Word demo - Article describing the trick (@Klewos).
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